Two problems:
1. You have used quotation marks around floating point numbers in these parts: 
Code:if temp = '25.0' and v_b = '0.0' then 
2. Conditional instantiation needs to be done with 
generate clauses rather than if then else statements.
Note I'm not particular VHDL literate, but from a quick look at a VHDL book and some testing in AMS Designer (I think you're using something different) I can get it to compile with: 
Code:library IEEE;
library EDULIB;
use IEEE.ELECTRICAL_SYSTEMS.all;
use IEEE.THERMAL_SYSTEMS.all;
use IEEE.std_logic_1164.all;
use IEEE.std_logic_unsigned.all;
entity Cap_model is
 generic (
   cap: CAPACITANCE := 471.0;
   temp: TEMPERATURE := 0.0;   -- Temperature @ 25C,125C & -55C
   v_b: VOLTAGE := 0.0     -- Bias Voltage @ 0V,25V,50V,75V and 95V
 );
 port (
   terminal p1: ELECTRICAL;
   terminal p2: ELECTRICAL
 );
end entity Cap_model;
architecture default of Cap_model is
     TERMINAL V_IN:      ELECTRICAL;
       TERMINAL V_RES2:      ELECTRICAL;
       TERMINAL V_MID:      ELECTRICAL;
       TERMINAL V_RES:      ELECTRICAL;
       TERMINAL V_RES1:      ELECTRICAL;
       ALIAS ground is ELECTRICAL_REF;
begin
G1: if temp = 25.0 and v_b = 0.0 generate
 C1: entity EDULIB.capacitor(Ideal)
         generic map (cap => 0.00000000046521)
     port map (p1 => V_RES,p2 => ELECTRICAL_REF);
 C2: entity EDULIB.capacitor(Ideal)
     generic map (cap => 0.0000000000065)
     port map (p1 => V_RES2,p2 => ELECTRICAL_REF);
 R1: entity EDULIB.resistor(ideal)
     generic map (res => 1850.0)
     port map (p1 => V_RES1,p2 => V_RES);
 R2: entity EDULIB.resistor(ideal)
     generic map (res => 562.69)
     port map (p1 => V_RES2,p2 => V_MID);
 L1: entity EDULIB.inductor(Ideal)
     generic map (Ind => 0.000000000041)
     port map (p1 => V_MID,p2 => V_IN);
 L2: entity EDULIB.inductor(Ideal)
     generic map (Ind => 0.000000000779)
     port map (p1 => V_RES,p2 => V_MID);
end generate ;
G2: if temp = -55.0 and v_b = 25.0 generate
 C1: entity EDULIB.capacitor(Ideal)
         generic map (cap => 0.00000000040123)
     port map (p1 => V_RES,p2 => ELECTRICAL_REF);
 C2: entity EDULIB.capacitor(Ideal)
     generic map (cap => 0.0000000000065)
     port map (p1 => V_RES2,p2 => ELECTRICAL_REF);
 R1: entity EDULIB.resistor(ideal)
     generic map (res => 6300.0)
     port map (p1 => V_RES1,p2 => V_RES);
 R2: entity EDULIB.resistor(ideal)
     generic map (res => 1800.00)
     port map (p1 => V_RES2,p2 => V_MID);
 L1: entity EDULIB.inductor(Ideal)
     generic map (Ind => 0.000000000041)
     port map (p1 => V_MID,p2 => V_IN);
 L2: entity EDULIB.inductor(Ideal)
     generic map (Ind => 0.000000000779)
     port map (p1 => V_RES,p2 => V_MID);
end generate;
end architecture default;
 
(well, I didn't have the sub-cells, but it got rid of all the other errors, which were very similar to the errors you were seeing).
Note doing = comparisons on real numbers is never a good idea, although I guess these are likely to be literal values, so may be OK.
Regards,
Andrew.