RFICDUDE
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I good practical book on the characteristics and spectrum of modulated signals is Earl McCunes book
Practical Digital Wireless Signals Earl McCune Cambridge Publishing
There is a paperback version that is scheduled for release in August 2013, but the hardback has been available for a few years.
MATLAB is good tool, but there are other expensive tools out there. ADS Ptolemy Ansys DesignerRF AWR Visual System Simulator
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